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81.
Yiheng Wei Bin Du Songsong Cheng Yong Wang 《Journal of Optimization Theory and Applications》2017,174(1):122-138
This paper deals with the time-optimal control problem for a class of fractional order systems. An analytic solution of the time-optimal problem is proposed, and the optimal transfer route is provided. Considering it is usually adopted in the discrete situation for actual control system, the sampling date may induce chattering phenomenon, an alternative sub-optimal solution is constructed. Additionally, the special and meaningful application of fractional order tracking differentiator is introduced to explain our main results. The effectiveness and advantages of the proposed method have been illustrated by numerical examples. 相似文献
82.
Nikolaos S. Papageorgiou Vicenţiu D. Rădulescu Dušan D. Repovš 《Journal of Optimization Theory and Applications》2017,175(2):293-323
We consider a nonlinear, nonhomogeneous Robin problem with an indefinite potential and a nonsmooth primitive in the reaction term. In fact, the right-hand side of the problem (reaction term) is the Clarke subdifferential of a locally Lipschitz integrand. We assume that asymptotically this term is resonant with respect the principal eigenvalue (from the left). We prove the existence of three nontrivial smooth solutions, two of constant sign and the third nodal. We also show the existence of extremal constant sign solutions. The tools come from nonsmooth critical point theory and from global optimization (direct method). 相似文献
83.
84.
In this paper, we obtain universal inequalities for the eigenvalues of the Dirichlet problem and clamped plate problem of drifting Laplacian on (\(n+1\))-dimensional (\(n\ge 4\)) complete noncompact simply connected smooth metric measure spaces which meet some conditions of the sectional curvature and radial weighted Ricci curvature. 相似文献
85.
Yubo Shao Jing Du Hua Li Yongqing Zhao Cailing Xu 《Journal of Solid State Electrochemistry》2017,21(1):183-192
A series of Ni0.37Co0.63S2-reduced graphene oxide nanocomposites with different graphene contents (NCS@rGO-x) has been successfully prepared via a facile one-step hydrothermal method and applied as the catalysts for the oxygen evolution reaction (OER) and degradation of organic pollutants. The XRD and FESEM analyses revealed that the phase structure and morphology of NCS nanoparticles were substantially influenced by the graphene contents. The phase structure of NCS nanoparticles gradually transformed from primary NiCo2S4 to Ni0.37Co0.63S2 and the morphology and size of NCS nanoparticles were found to become more regular and homogeneous with the increase of graphene concentration. On the NCS@rGO-x nanocomposites, the NCS@rGO-2 sample demonstrated the best catalytic activity toward the OER, which delivers a stable current density of 10 mA cm?2 at a small overpotential of ~276 mV (vs. RHE) with a Tafel slope as low as 48 mV dec?1. Furthermore, the NCS@rGO-2 sample showed the remarkable photocatalytic activity for degradation of methylene blue (MB), which may be attributed to the increased reaction sites and high separation efficiency of photogenerated charge carries due to the electronic interaction between NCS nanoparticles and rGO. All these impressive performances indicate that the NCS@rGO-2 nanocomposite is a promising catalyst in energy and environmental fields. 相似文献
86.
Xuan Shen Xiaohong Xia Weichun Ye Yongling Du Chunming Wang 《Journal of Solid State Electrochemistry》2017,21(2):409-417
Hexagram-like CoS-MoS2 composites were prepared on indium tin oxide (ITO) conductive glasses via cyclic voltammetry electrodeposition using Co(NO3)2 and (NH4)2MoS2 as precursors and tested for application in hydrogen evolution reaction (HER). The structure of CoS-MoS2 composites was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and X-ray photoelectron spectrum (XPS). Electrochemical characterizations indicate that CoS-MoS2 composites exhibit more excellent catalytic activity and stability than MoS2. Compared with pure MoS2, the hexagram-like CoS-MoS2 composites with increased specific surface area improved the density of exposed active sites, and the Co binding S edges in CoS-MoS2 composites promote the number of highly catalytic edge sites and decreased the binding energy △G H. Moreover, the effects of different substrates on the CoS-MoS2 composites were also investigated. Our further understanding of this highly active hydrogen evolution catalyst can facilitate the development of economical electrochemical hydrogen production systems. 相似文献
87.
In this paper, the nonlinear iterative methods, which are different from the classical algorithms, to solve inverse problems are presented. Our methods by denoting some parameters and some properties of the algorithm in both noise and noiseless cases are studied. Finally, the convergence of the sequence generated by the algorithm without noise is discussed. 相似文献
88.
Home owners are typically charged differently when they consume power at different periods within a day. Specifically, they are charged more during peak periods. Thus, in this paper, we explore how scheduling algorithms can be designed to minimize the peak energy consumption of a group of homes served by the same substation. We assume that a set of demand/response switches are deployed at a group of homes to control the activities of different appliances such as air conditioners or electric water heaters in these homes. Given a set of appliances, each appliance is associated with its instantaneous power consumption and duration, our objective is to decide when to activate different appliances in order to reduce the peak power consumption. This scheduling problem is shown to be NP-Hard. To tackle this problem, we propose a set of appliance scheduling algorithms under both offline and online settings. For the offline setting, we propose a constant ratio approximation algorithm (with approximation ratio \(\frac{1+\sqrt{5}}{2}+1\)). For the online setting, we adopt a greedy algorithm whose competitive ratio is also bounded. We conduct extensive simulations using real-life appliance energy consumption data trace to evaluate the performance of our algorithms. Extensive evaluations show that our schedulers significantly reduce the peak demand when compared with several existing heuristics. 相似文献
89.
中国战略性新兴产业国际竞争力评价 总被引:1,自引:0,他引:1
以"新钻石模型"为基础,从产业环境、产业支撑和产业创新等3个维度构建战略性新兴产业国际竞争力评价指标体系.运用2005~2014年的面板数据对战略性新兴产业进行因子分析.评价结果显示,电子及通信设备制造业与医药制造业国际竞争力明显高于计算机及办公设备制造业与医疗仪器设备及仪器仪表制造业.航空航天器及设备制造业国际竞争力有很大提升潜力.电子及通信设备制造业创新能力表现突出,但战略性新兴产业整体创新能力较低. 相似文献
90.
Shaopeng Li Jing Du Bin Zhang Yanzhen Liu Qingqing Mei Qinglei Meng Minghua Dong Juan Du Zhijuan Zhao Lirong Zheng Buxing Han Meiting Zhao Huizhen Liu 《物理化学学报》2023,38(10):2206019
Selective hydrogenation is a vital class of reaction. Various unsaturated functional groups in organic compounds, such as aromatic rings, alkynyl (C≡C), carbonyl (C=O), nitro (-NO2), and alkenyl (C=C) groups, are typical targets in selective hydrogenation. Therefore, selectivity is a key indicator of the efficiency of a designed hydrogenation reaction. 5-(Hydroxymethyl)furfural (HMF) is an important platform compound in the context of biomass conversion, and recently, the hydrogenation of HMF to produce fuels and other valuable chemicals has received significant attention. Controlling the selectivity of HMF hydrogenation is paramount because of the different reducible functional groups (C=O, C-OH, and C=C) in HMF. Moreover, the exploration of new routes for hydrogenating HMF to valuable chemicals is becoming attractive. 5-Methylfurfural (MF) is also an important organic compound; thus, the selective hydrogenation of HMF to MF is an essential synthetic route. However, this reaction has challenging thermodynamic and kinetic aspects, making it difficult to realize. Herein, we propose a strategy to design a highly efficient catalytic system for selective hydrogenation by exploiting the synergy between steric hindrance and hydrogen spillover. The design and preparation of the Pt@PVP/Nb2O5 catalyst (PVP = polyvinyl pyrrolidone; Nb2O5 = niobium(V) oxide) were also conducted. Surprisingly, HMF could be converted to MF with 92% selectivity at 100% HMF conversion. The reaction pathway was revealed through the combination of control experiments and density functional theory calculations. Although PVP blocked HMF from accessing the surface of Pt, hydrogen (H2) could be activated on the surface of Pt due to its small molecular size, and the activated H2 could migrate to the surface of Nb2O5 through a phenomenon called H2 spillover. The Lewis acidic surface of Nb2O5 could not adsorb the C=O group but could adsorb and activate the C-OH group of HMF; therefore, when HMF was adsorbed on Nb2O5, the C-OH groups were hydrogenated by the spilled over H2 to form MF. The high selectivity of this reaction was realized because of the unique combination of steric effects, hydrogen spillover, and tuning of the electronic states of the Pt and Nb2O5 surfaces. This new route for producing MF has great potential for practical application owing to its discovered advantages. We believe that this novel strategy can be used to design catalysts for other selective hydrogenation reactions. Furthermore, this study demonstrates a significant breakthrough in selective hydrogenation, which will be of interest to researchers working on the utilization of biomass, organic synthesis, catalysis, and other related fields.
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